FSD100MbP?h㈵>d dfffffr@ Frank EckertCOSMOlogic GmbH & Co KGThis is a simple stream and phase diagram of the binary system methanoland water, where activity coefficients are computed by the COSMOthermCO model vie CAPE-OPEN. COSMOthermCO is a liquid thermodynamic method based on molecular interactions computed by ab initio quantum chemistry.A,CTڐ@'t+B/>/CTư>MbP?MbP?MbP?K2C:\Program Files\COCO\data\DefaultComponentLib.pcd.WaterHOHH2O 7732-18-5O9 9@ uAz?@O?`fRw@`fq@`q@@2@ ??=@X@ I9@qU?AӬ`@ AVA@_tA{J@` 8 8 8$m@`fq@`w?P?`f:@`?Qa@3o@Q:@i@X@̨%Ա>@`frp@Q:@eDȍAo_??`2ֿ`fq@=:@j)hp࣐a@MоI =@33 @`fq@d0q@@a@eпf'?q@@3@@/@`0;@@`3c?I@@@4?`6l2vG)@`fq@@@h`f`@@Qx2@`T@q@@ 9@e@r>?`ff@ 8`q@Đ@f}@ K? R?sq@@3Ƀ@`1>P? /M@> 8`q@Đ@fId@.n v?`p@@ 9@@fA`? k !@6l>I@@@d 8 8 8 8 8 8 8f7@&@zB 8 8)tx@@3@ ZWt l> 8 8q@@ 9@ :#J{#Q@\yf8TBfm?w-! b=@p?`ff???`X@B? 8 8 8 AN? 8έ?`?@by?Q8*@ ?@1(@8@x ?(?B?;MethanolCH3OHCH4O67-56-1COM, @:^A?5?@?@ u@@ e@@ e@ {?@`@@ڤ?z?`T=@9`%;?VA3Y@H ALHA΀A`•>@W 8 8 8dd@̔e@6??@? 8@ e@q@i`f^@@3.`U>@@ e@@e(A?-??@ e@@3 @j@3Ɍ@o2w?>9@@3c@d@̘@_?@@ e@y@ @3s-@ 1&@@qO?@הY@p@L0hC@?W@R`fq@p@h|@@ @vо@@ e@u@e Q> bJ?כi@M8@ 8n@@@f @O*@ڊ2`_b@z@K> C? [@@ 8q@b@f2@@@@qP?¾q@`fr@@#@@ M]h?58`U!>I@@@d 8 8 8 8 8 8 8Z7@ƫ@ ݔB 8 8`f>s@|@ @*? 8 8@ e@u@ 㥛 u@ X4?#~jL|sj1@G?G?Q?@?@֤? 8 8 8`?6? 8!S? k?¯?@?@ڤ?D @z@)Տ?@?֤? CosmoTherm4qXnJ5/activityactivityCoefficientactivityactivityCoefficientNnocoMETHANOLMethanolWATERWateractivityactivityactivityCoefficientactivityCoefficientbubblePointPressurebubblePointPressurebubblePointTemperaturebubblePointTemperaturedensitydensitydensity/volume (pure)density/volume (pure)dewPointPressuredewPointPressuredewPointTemperaturedewPointTemperature enthalpyenthalpyentropyentropy:: excessEnthalpyexcessEnthalpyfugacityfugacityfugacityCoefficientfugacityCoefficientgibbsFreeEnergy gibbsEnergyGG heatCapacityheatCapacityCpKK heatOfVaporizationheatOfVaporizationidealGasEnthalpyidealGasEnthalpyidealGasEntropyidealGasEntropyJkvalueskvalueI logFugacityCoefficientlogFugacityCoefficient logkvalues logkvalueImolecularWeightmolecularWeightHHHsurfaceTensionsurfaceTensionsurfaceTension (pure)surfaceTension (pure)thermalConductivitythermalConductivity04thermalConductivity (pure)thermalConductivity (pure))1 vaporPressure vaporPressure viscosity viscosity& viscosity (pure)viscosity (pure)" volumevolumeVapor Vapor phaseLiquid Liquid phase  oŏ1?Methanol/Water p61 1/1aimported from NRTL.IPDoŏ1?Methanol/Water p61 1/1aimported from NRTL.IPD 333333? Water/waterimported from HAYDENO.IPD?Water/methanolimported from HAYDENO.IPD?Water/methanolimported from HAYDENO.IPDGz?Methanol/methanolimported from HAYDENO.IPD g곿Methanol/Water p730imported from PR.IPD g곿Methanol/Water p730imported from PR.IPD†W2Methanol/Water p730imported from SRK.IPD†W2Methanol/Water p730imported from SRK.IPD†W2Methanol/Water p730imported from SRK.IPD†W2Methanol/Water p730imported from SRK.IPDH}8?Methanol/Waterimported from VANLAAR.IPD?ܵ?Methanol/Waterimported from VANLAAR.IPD:M?Methanol/Waterimported from MARGULES.IPDH?Methanol/Waterimported from MARGULES.IPDPgkYn@Methanol/Waterimported from WILSON.IPD-QY@Methanol/Waterimported from WILSON.IPD\Ux@Methanol/Water p61 1/1aimported from NRTL.IPD4ЄWMethanol/Water p61 1/1aimported from NRTL.IPD u`Iq@Methanol/Water (Kojima+Kato)imported from UNIQUAC.IPDG} o8eMethanol/Water (Kojima+Kato)imported from UNIQUAC.IPD u`Iq@Methanol/Water (Kojima+Kato)imported from UNIQUAC.IPDG} o8eMethanol/Water (Kojima+Kato)imported from UNIQUAC.IPDH2OCH3OHH2Oq= ףp?ffffff?jt2@CH3OH?x?L7A`@@r@fH2OCH2OHH2Oq= ףp?ffffff?jt2@CH3ͪ?A`"? rh.@OH?333333?5^I 1@ffffffu@^P@$@{G<@33333t@ V瞯<activity.Dtemperatureactivity.Dtemperatureactivity.Dpressureactivity.Dpressureactivity.DmolFractionactivity.DmolFraction activityCoefficient.Dtemperature activityCoefficient.DtemperatureactivityCoefficient.DpressureactivityCoefficient.Dpressure activityCoefficient.DmolFraction activityCoefficient.DmolFractionCT 7732-18-5Water2@CTWater67-56-1Methanol@`@@CTMethanol activity.Dtemperature logFugacityCoefficient.Dpressure volume.Dmoles@@activity.DmolFractionenthalpy?idealGasEntropy?excessEnthalpy.Dpressure?heatOfVaporization.Dmoles?#logFugacityCoefficient.Dtemperaturelogkvalues.DpressuremolecularWeight.Dmoles / molvolume.Dtemperature@@ activityCoefficient.Dtemperatureentropy.Dmoles? heatCapacity?heatCapacity.DmolFraction?heatCapacity.Dtemperature?heatOfVaporization.Dpressure?#logFugacityCoefficient.DmolFractionthermalConductivity?volume.DmolFraction@@activity.Dpressure activityCoefficient.DmolFractiondensity.Dpressure?@logFugacityCoefficient.Dmoles / molsurfaceTension?density?@fugacityCoefficient.Dmoles / molgibbsFreeEnergy.Dpressure?molecularWeightthermalConductivity.Dpressure?surfaceTension.Dtemperature?activityCoefficient.DpressureexcessEnthalpy.Dmoles?fugacity.Dpressure fugacityCoefficient.DtemperaturegibbsFreeEnergy?heatOfVaporization.Dtemperature? logkvaluessurfaceTension.DmolFraction?activityCoefficient.Dmoles / molenthalpy.Dmoles? fugacityCoefficient.DmolFractionheatOfVaporization.DmolFraction?idealGasEntropy.Dtemperature?kvaluessurfaceTension.Dmoles? / molviscosity.Dpressure?viscosity.Dtemperature??density.Dmoles?@ / molgibbsFreeEnergy.Dmoles?kvalues.Dmoles / molthermalConductivity.Dmoles? / molviscosity.DmolFraction??activitylogkvalues.Dmoles / molvolume@@enthalpy.Dtemperature?fugacity.Dmoles? / mol viscosity??volume.Dpressure@@enthalpy.DmolFraction?excessEnthalpy.Dtemperature?heatCapacity.Dmoles?logkvalues.DtemperaturesurfaceTension.Dpressure?density.Dtemperature?@enthalpy.Dpressure?entropy.Dpressure?excessEnthalpy.DmolFraction?fugacityCoefficient.DpressureidealGasEnthalpy.Dtemperature?kvalues.Dtemperaturelogkvalues.DmolFractionmolecularWeight.Dpressureactivity.Dmoles / molactivityCoefficientdensity.DmolFraction?@entropy?heatCapacity.Dpressure?idealGasEnthalpy?kvalues.DmolFractionentropy.Dtemperature?excessEnthalpy?fugacity.Dtemperature?gibbsFreeEnergy.Dtemperature?kvalues.DpressuremolecularWeight.Dtemperature thermalConductivity.Dtemperature?vaporPressure.Dtemperature?viscosity.Dmoles?? / molentropy.DmolFraction?fugacityCoefficientgibbsFreeEnergy.DmolFraction?heatOfVaporization?logFugacityCoefficientmolecularWeight.DmolFraction thermalConductivity.DmolFraction?iactivityactivity.Dmolesactivity.DmolFractionactivity.Dpressureactivity.DtemperatureactivityCoefficientactivityCoefficient.Dmoles activityCoefficient.DmolFractionactivityCoefficient.Dpressure activityCoefficient.DtemperaturebubblePointPressurebubblePointTemperaturedensitydensity.Dmolesdensity.DmolFractiondensity.Dpressuredensity.DtemperaturedewPointPressuredewPointTemperatureenthalpyenthalpy.Dmolesenthalpy.DmolFractionenthalpy.Dpressureenthalpy.Dtemperatureentropyentropy.Dmolesentropy.DmolFractionentropy.Dpressureentropy.DtemperatureexcessEnthalpyexcessEnthalpy.DmolesexcessEnthalpy.DmolFractionexcessEnthalpy.DpressureexcessEnthalpy.Dtemperaturefugacityfugacity.Dmolesfugacity.DmolFractionfugacity.Dpressurefugacity.DtemperaturefugacityCoefficientfugacityCoefficient.Dmoles fugacityCoefficient.DmolFractionfugacityCoefficient.Dpressure fugacityCoefficient.DtemperaturegibbsFreeEnergygibbsFreeEnergy.DmolesgibbsFreeEnergy.DmolFractiongibbsFreeEnergy.DpressuregibbsFreeEnergy.Dtemperature heatCapacityheatCapacity.DmolesheatCapacity.DmolFractionheatCapacity.DpressureheatCapacity.DtemperatureheatOfVaporizationheatOfVaporization.DmolesheatOfVaporization.DmolFractionheatOfVaporization.DpressureheatOfVaporization.DtemperatureidealGasEnthalpyidealGasEnthalpy.DtemperatureidealGasEntropyidealGasEntropy.Dtemperaturekvalueskvalues.Dmoleskvalues.DmolFractionkvalues.Dpressurekvalues.DtemperaturelogFugacityCoefficientlogFugacityCoefficient.Dmoles#logFugacityCoefficient.DmolFraction logFugacityCoefficient.Dpressure#logFugacityCoefficient.Dtemperature logkvalueslogkvalues.Dmoleslogkvalues.DmolFractionlogkvalues.Dpressurelogkvalues.DtemperaturemolecularWeightmolecularWeight.DmolesmolecularWeight.DmolFractionmolecularWeight.DpressuremolecularWeight.DtemperaturesurfaceTensionsurfaceTension.DmolessurfaceTension.DmolFractionsurfaceTension.DpressuresurfaceTension.DtemperaturethermalConductivitythermalConductivity.Dmoles thermalConductivity.DmolFractionthermalConductivity.Dpressure thermalConductivity.Dtemperature vaporPressurevaporPressure.Dtemperature viscosityviscosity.Dmolesviscosity.DmolFractionviscosity.Dpressureviscosity.Dtemperaturevolume volume.Dmolesvolume.DmolFractionvolume.Dpressurevolume.DtemperatureVaporCTVaporLiquidCTLiquid VaporLiquiddefaultdefault material templateCT1"7"(""7""7" NCalcEquilibrium failed: calcEquilibrium failed: tp flash failed: failed to obtain logFugacityCoefficient or one of its derivatives from a calculation material for the Liquid phase: Activity calculation failed: CTD file "C:\Programme\COSMOthermCO-LITE-C21-0107\CTDATA-FILES\BP_TZVP_C21_0106.ctd" does not exist or is not a regular file (P)*@,defaultм@0v@?V-??n??~8{?iKk?:n? =$?䠋?y?lQYR?wHM?0]YGQ?&"?EMq]??n??~8{?0v@м@?V-?2MS Sans -C6?-C6?h㈵>-C6?U::Composition Plot Methanol/Water N-Yo? X?MethanolWaterArialArialArialMole fraction Methanol;Oz@1????Mole fraction MethanolActivityCoefficient:g1Z@v?SZ@??v?SZ@??ActivityCoefficientactivityCoefficient-Liquid activityCoefficient(Water), stream "1"1??Z'%?0.++ЗXUU?ЗXUU?1?ЗXUU?#?1?ḓ?ЗXUU??#?0AZUU?1?Y=XUU?ḓ?SZ?ЗXUU?M1x??GdYUU?#?A?0AZUU?;ϯ?1???IYC?S2.?mO.?F#?wFy?F?a=*?-Ђ?! `?(Nn̶1?Bu??^[.?y?^?|gy?\0?l?)^_?x2?@g{N?ۉ?XB?Z'%?activityCoefficientWaterLiquid0Liquid activityCoefficient(Methanol), stream "1"1??>]@Q@0.++ЗXUU?ЗXUU?1?ЗXUU?#?1?ḓ?ЗXUU??#?0AZUU?1?Y=XUU?ḓ?SZ?ЗXUU?M1x??GdYUU?#?A?0AZUU?;ϯ?1?>]@Q@8]3l@Hw?n4ߊ?i H?Q`]?E6k?C[?v٨6 ?4h? V*?y}?pt*?*٘X???=?sCb?UF?@Q^' 1?1!# ?{.]?oH"I ?>oL?jj??activityCoefficientMethanolLiquid